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Title
The Role of Porosity and Surface Morphology of Calcium Carbonate Deposits on the Corrosion Behavior of Unprotected API 5L X52 Rotating Disk Electrodes in Artificial Seawater
Type of Research Article
Keywords
Calcium carbonate deposits, Cathodic protection, Porosity, Steel Surface morphology
Abstract
The role of porosity of calcium carbonate deposits on the corrosion performance of API 5L X52 steel was investigated by chronoamperometry, Electrochemical Impedance Spectroscopy (EIS), Scanning Electron Microscope/Energy Dispersive Spectroscopy and X-Ray Diffraction. EIS analysis showed that calculation of the area under Bode phase diagrams in high frequency domain is the best electrochemical approach for porosity percentage estimation. Applied potential has the most significant influence on porosity percentages. The least amount of porosity can be obtained by an interactive process at less negative potentials and more rotation speeds, i.e. −1.0 VSCE and 600 rpm resulting in a uniform and compact layer of aragonite crystals.
Researchers Seyyed Morteza Hoseinieh (First Researcher)، Taghi Shahrabi (Second Researcher)، Bahram Ramezanzadeh (Third Researcher)، Morteza Farrokhi-rad (Fourth Researcher)