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Title
Synthesis and characterization of poly (1‐vinyl‐3‐ butylimidazolium‐co‐methyl methacrylate) gel polymer electrolytes for dye‐sensitized solar cells: Effect of structure and composition
Type of Research Article
Keywords
dye‐sensitized solar cells
Abstract
Herein, three ionic liquid random copolymers (P) containing 1‐vinyl‐3‐ butylimidazolium bromide (VBImBr) and methyl methacrylate (MMA) with various molar ratios were prepared using conventional free radical polymerization. Afterward, their corresponding chemically cross‐linked copolymers (XP) were formed similarly in the presence of polyethylene glycol dimethacrylate (PEGDMA). The synthesized copolymers were characterized using FT‐IR, 1H NMR, and GPC. Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) results showed that the rigidity and thermal stability of the copolymers depended on the ionic liquid content as well as the degree of cross‐linking. Gel polymer electrolytes were then prepared via obtained copolymers in the presence of a constant amount of synthesized imidazolium‐based ionic liquid. Among the copolymers, the P3 with in feed VBImBr: MMA molar ratio of 70:30 and the cross‐linked 1%‐XP3 copolymer prepared with 1 mol% of PEGDMA exhibited the highest conductivity and diffusion coefficients for I3 ¯ and I¯. The power conversion efficiency of the optimized linear and crosslinked copolymers (P3 and 1%‐XP3) under the simulated AM 1.5 solar spectrum irradiation at 100 mW cm−2 were 3.49 and 4.13% in the fabricated dye‐sensitized solar cells (DSSCs), respectively. The superior long‐term stability and high performance of the gel electrolyte containing 1%‐XP3 suggested it as commercial gel electrolyte for future DSSCs.
Researchers (First Researcher)، Massoumeh Bagheri (Second Researcher)، Rahim Mohammad-Rezaei (Third Researcher)