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Abstract
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Recently, the demand for newrenewable and sustainable polymers, aswell as their use as precursors to produce ener
getic materials, has emerged as a popular and burgeoning area of study. In this study, novel energetic nitrogen-rich polymers
based on the 1,3,5-triazine ring were synthesized utilizing standard techniques. Four monomers were created initially: 4,6-
dichloro-N-(4-chlorophenyl)-1,3,5-triazine-2-amine (A), 1,1’-bis(4,6-dichloro-1,3,5-triazine-2-yl)-1H,1’H-5,5’-bitetrazole
(B), 2,4,6-trihydrazinyl-1,3,5-triazine (C),N-(4-chlorophenyl)-4,6-dihydrazinyl-1,3,5-triazin-2-amine (D) In the second step,
seven novel polymers named CHTA, TBT, TBTH, CTBT, THT, CTC, and TCT were synthesized via polyaddition reactions
with monomers. Infra-red spectroscopy was used to characterize the nitrogen-rich polymers that were formed (IR). TGA
measurements were utilized to investigate the thermal stability of substances. In addition, SEM and 1HNMR were utilized
to describe the compounds. The results of thermal analysis indicate that TBT, CTC, and TCT are less stable than other
nitrogen-rich polymers. The reaction yield for synthesized energetic polymer were 73%, 92%, 67%, 80%, 84%, 72% and
74% for CHTA, TBT, TBTH, CTBT, THT, CTC and TCT respectively
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