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Title
Facile and efficient stereospecific deamination of aziridines using task‑specific silica immobilized organosilane‑based nitrite ionic liquid
Type of Research Article
Keywords
Aziridine · Deamination · Nitrite-ionic liquid · Solvent-free
Abstract
Various cis- and trans-aziridine derivatives were deaminated via the reaction with task-specific silica immobilized organosilane- based nitrite ionic liquid. Corresponding cis- or trans-alkenes were produced as stereospecific products in goodto- excellent yields. The advantages of this method include the one-pot procedure, operational simplicity, solvent-free, and very short reaction times. Simple handling of this nitrite anion source nanoparticles and thus lowering the risks and hazards of a chemical process can offer other important advantages.
Researchers Hassan Valizadeh (First Researcher)، (Second Researcher)