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Title
Determination of trace amounts of Mo(VI) in water by combining dispersive surfactant micelle-mediated extraction with the fluorescence properties of carbon quantum dots
Type of Research Presentation
Keywords
Carbon quantum dots, fluorescence emission, Molybdenum(VI)
Abstract
Nanotechnology is the application of scientific knowledge to manipulate and control matter at the nanoscale in order to make use of size- and structure-dependent properties and phenomena, as distinct from those associated with individual atoms or molecules or with bulk materials [1]. Carbon dots (CDs), as a new class of functional carbon nanomaterials, have been attracting tremendous attention due to their unique optical properties coupled with low toxicityand facile functionalization. This has led to numerous possible applicationsinsensing, bioimaging and the develop ment of optoelectronic devices [2]. Molybdenum is an essential trace element for both plants and animals, including humans. However, it appears to be toxic when its concentration in plants is higher than 5 μg.g-1, whereas potential toxicity for ruminants equals to 10 μg.g-1. Also, due to the good resistance of molybdenum to corrosion as well as the melting point, high strength and thermal conductivity, this element is widely used in various industries. Therefore, the high risk of environmental pollution around such industries makes the measurement of molybdenum in plant and biological samples important [3]. In the current research, red emissive carbon quantum dots used to determine molybdenum(VI) in aqueous media. In this way, the analyte was first separated and concentrated using green extraction methods based on cetyltrimethyl-ammonium bromide (CTAB) surfactant, and then it was dissolved in ethanol medium and measured. The linear range and detection limit of the proposed method for measuring molybdenum (VI) were 5-50 μg.L-1 and 2 μg.L-1, respectively.
Researchers Leila Khoshmaram (First Researcher)، Mohammad Hoseinvand Navidian (Second Researcher)