مشخصات پژوهش

صفحه نخست /CeO2/mixed transition metal ...
عنوان
CeO2/mixed transition metal oxide nanostructures immobilized on Ti3C2TX MXene for boosting electrochemical water oxidation
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
2D Ti3C2TX MXene CeO2/NiO/Co3O4@MXene nanocomposites Water splitting Electrocatalyst
چکیده
Metal oxides on MXene layers are used as efficient electrode materials for water oxidation. In this study, CeO2/NiO/Co3O4@MXene (CNCM) nanocomposites were synthesized and investigated as modified nickel foam (NF) electrodes for water oxidation. In a 1.0 M KOH electrolyte solution, the CNCM(5:1) nanocomposite achieved a low overpotential of 365 mV at a current density of 100 mA cm−2, a Tafel slope of 57 mV dec−1, and a charge transfer resistance of 0.39 Ω cm2. It demonstrated significantly improved performance compared to its constituents and other combinations with the same weight ratio of nanoparticles to MXene. CNCM(5:1) also exhibited high stability during chronopotentiometry at a current density of 25 mA cm−2 over 24 h. Furthermore, it effectively served as both anode and cathode materials in an overall water splitting (OWS) system, achieving a cell voltage of 1.83 V and maintaining stability for at least 10 h.
پژوهشگران زهره شقاقی سراسکانرود (نفر اول)، سحر جعفری (نفر دوم)، علیرضا ختائی (نفر سوم)