کلیدواژهها
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Nonlinear optical property, nonlinear refraction, linear absorption, thiomolybdate complexes, N,S-donor ligands
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چکیده
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In this research, two new polynuclear complexes of thiomolybdate homologous (Et4N)2[MoS4(Cu-L1)2] (1) and (Et4N)2[MoS4(Cu-L2)2] (2) with N,S-donor amino dithioate ligands comprise L1 = 2-aminocyclopent-1-enecarbodithioate, L2 = 2-aminocyclohex-1- enecarbodithioate are synthesized and characterized with are synthesized and characterized with FT-IR, 1
HNMR, 13
CNMR, Uv-Visible and elemental analysis. Nonlinear optical properties of these complexes include linear absorption coefficient (α) and third-order nonlinear refractive index (n2) are investigated by Z-scan method under irradiation of low power 35 mW continuous wave He–Ne Laser. The optical limiting behavior is investigated by transmission measurement through the samples
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