مشخصات پژوهش

صفحه نخست /A template-free method to ...
عنوان
A template-free method to synthesize porous G-C3N4 with efficient visible light photodegradation of organic pollutants in water
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Photocatalysis Graphitic carbon nitride Dye degradation Rhodamine B Zeta potential
چکیده
Porous graphitic carbon nitride with a high surface area was successfully synthesized without using any template or other substances like metals, just by placing melamine powder into a muffle furnace which was heated to 550 C in advance. To evaluate the structure, morphology, and optical properties, the high performance g-C3N4 (HPCN) was analyzed by XRD, SEM-EDX, TEM, N2 physisorption, FT-IR analysis, UV–Vis DRS, PL, and Zeta potential. HPCN was able to completely degrade rhodamine B under visible light with the rate constant of 0.086 min1, which is 3.5 times higher than the traditional g-C3N4. The possible mechanism of RhB photodegradation was discussed in detail, which illustrated the reaction is performed in acidic media much better than neutral and basic solutions, and O2 and h+ are the key reactive species during the reaction. Moreover, the stability of the photocatalyst was investigated and turned out its pho- tocatalytic activity has not considerably changed after 6 cycles, so it was a highly stable photocatalyst. ! 2018 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
پژوهشگران الهام بوبور عظیمی (نفر اول)، علیرضا بدیعی (نفر دوم)، مؤید حسینی صدر (نفر سوم)، احمد امیری (نفر چهارم)