کلیدواژهها
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Magnesium silicate hydrate, Magnesium aluminate hydrate, Highly plastic fine-grained clayey soils, Magnesium chloride (MgCl2), Clay mineralogy, Soil microstructure, Soil stabilization,
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چکیده
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In recent years, there has been an increasing interest in investigating the use of non-traditional additives for
stabilizing problematic soils. As the demand for eco-friendly alternatives to cement rises, magnesium chloride, a
widely used deicer and dust suppressor, has emerged as a potential choice. This study aims to provide a
comprehensive understanding of the microstructural changes that occur and affect the macro behavior of treated
bentonite (B) and yellow marl (YM). To achieve this, MgCl2 solution was added to the soils at 3, 6, 9, and 12
percent by dry weight of the soil, and samples were cured for 7, 14, and 28 days at 5 ◦C, 25◦C, and 35 ◦C. The
mechanical properties of the treated soils were then evaluated using the unconfined compression test, direct
shear test, and pressure chamber test (SWCC), while microstructural analysis techniques such as X-ray diffraction
(XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX), and Fourier trans-
form infrared spectroscopy (FTIR) were employed to examine the mechanism of MgCl2 stabilization. The results
indicate that adding MgCl2 and extending the curing period significantly increased both soils’ unconfined
compressive strength (UCS). However, the UCS value decreased for treated samples cured at temperatures higher
than 25◦C due to an incomplete cation exchange process and the reduction of apparent cohesion. A part of the
gained strength from apparent cohesion and matric suction in the unsaturated samples was lost when the samples
reached full saturation during the direct shear test. Changes in the particle size, pore size, and pore void dis-
tribution due to the MgCl2 stabilization affected the SWCCs of the treated soils. Microstructural analyses revealed
the formation of magnesium hydration products, such as magnesium silicate hydrate (M-S-H) and magnesium
aluminate hydrate (M-A-H), which contributed to the strength increase by increasing grain size, filling the pores,
binding fine
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