مشخصات پژوهش

صفحه نخست /Photocatalytic activity ...
عنوان
Photocatalytic activity enhancement of carbon-doped g-C3N4 by synthesis of nanocomposite with Ag2O and α-Fe2O3
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
graphitic carbon nitride, kinetic study, nanocomposite, photocatalytic performance
چکیده
Carbon-doped g-C3N4 (CGNS) nanocomposite with Ag2O and α-Fe2O3 has been synthesized to improve g-C3N4 photocatalytic activity. The prepared CGNS/Ag2O/α-Fe2O3 (GAF [with mass ratio 3:2:1]) nanocomposite exhibits the expanded visible-light absorption region leading to the enhanced photocatalytic performance for Acid Red 14 (AR14) degradation. Besides, it is found that the recombination rate of the charge carriers effectively suppresses the nanocomposite. For a better understanding of the photocatalytic degradation mechanism, the reactions have been performed in the presence of different scavengers. The experiments indicate that superoxide anion radicals possess a more influential role in AR14 degradation in comparison with hydroxyl radicals and holes. The degradation efficiency has been decreased from 94.68 to 85.60 after five consecutive photocatalytic tests implying that the prepared nanocomposite is a stable photocatalyst. In the end, the kinetic study of AR14 degradation on nanocomposite with considering pseudo-first-order kinetics results in a nonlinear empirical kinetic model development for prediction of degradation efficiency of AR14 on nanocomposite.
پژوهشگران علیرضا امانی قدیم (نفر اول)، علیرضا طریقتی (نفر دوم)، نرگس نوزاد (نفر سوم)، هما محسنی زنوز (نفر چهارم)، سید مسعود سیداحمدیان (نفر پنجم)، میرسعید سید دراجی (نفر ششم به بعد)، محمد قلی نژاد (نفر ششم به بعد)، فرزانه بیات (نفر ششم به بعد)